A magnesiothermic reaction process for the scalable production of mesoporous silicon for rechargeable lithium batteries.

نویسندگان

  • An Xing
  • Jing Zhang
  • Zhihao Bao
  • Yongfeng Mei
  • Ari S Gordin
  • Kenneth H Sandhage
چکیده

Mesoporous, 3-D, nanocrystalline Si has been synthesized via the magnesiothermic reduction of SiO particles at a peak temperature of only 500 °C in a scalable flow-through reactor setup. Such 3-D porous Si as an anode material exhibited high, reversible capacities (i.e., >900 mA h g(-1) after 160 charge-discharge cycles at 1000 mA g(-1)).

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عنوان ژورنال:
  • Chemical communications

دوره 49 60  شماره 

صفحات  -

تاریخ انتشار 2013